I may be able to help you! I can share a little bit of what our toddler room at our high quality center has...
I know home & "school" is different but it might help you to get the ideas moving.
First we serve food (breakfast, snack, lunch, snack & late snack) every 2 hours! This is something i have transfered home! (i work 3 days a week, home the other 4) They go outside once in the am & once in the pm. They do several projects (art, science, math, language, world around us) they serve lunch, have a 2 hour nap period. They also change diapers every 2 hours per our state licensing.
So their day is filled with diapers, food, projects.
What time does your LO get up?
Does writing plans/ideas help you? I know for me, i sometimes need to commit to my schedule in writing to feel more accomplished.
Do you live near a library, Gymboree (or something where you have open gym etc), a YMCA?
Do you live in an area where you can get outside all year round?
I like doing my projects/errands etc in the morning.
So perhaps, i would run a toddler schedule like this:
wake up
breakfast
independent play
(so i could get dressed/ready)
out n about (hour-2 hours with drive time )
library-m
gym-tues
errands-wed
playdate-thur
Park-friday
Bringing a snack on the go with us
Home-
independent play until lunch
lunch
nap (i would try really hard to get a 2 hour nap/rest time in for child- i need that time to get dinner/laundry/exercise/rest)
project (great websites out there for SIMPLE & Easy toddler activities
play with mommy (cars, dolls, dramatic play-role play, balls, etc) (would alternate fine motor & large motor every other day...Fine motor- great example-threading beads on string (way advanced for most tods, just the example)
Large motor- active play-muscle development-outside time-kicking a ball, jumping, dancing etc
Independent play until dinner
Can you tell i love my job of working at a high quality child care center & that i help coordinate the lesson plans...i love sharing about curriculum and activities.
LOVE THIS WEBSITE (She's on this forums also :)
http://tvfreetoddlertime.blogspot.com/
If you are interested i can post projects that i teach in an activity class for parents.